{2-Hydroxy-6-[(2-oxidophenyl)iminomethyl-κ2 N,O]phenolato-κO 1}phenylboron
نویسندگان
چکیده
The [4.3.0]heterobicyclic title structure, C(19)H(14)BNO(3), is composed of a five-membered OBNC(2) ring and a six-membered OBNC(3) ring, each of which has an approximate envelope conformation. The coordination geometry of the B atom is distorted tetra-hedral. In the crystal structure, centrosymmetrically related mol-ecules are associated through pairs of O-H⋯O hydrogen bonds.
منابع مشابه
{4-Bromo-2-[(5-chloro-2-oxidophenyl)iminomethyl]phenolato-κ3 O,N,O′}(methanol-κO)(methanolato-κO)oxidovanadium(V)
The title Schiff base complex, [V(C(13)H(7)BrClNO(2))(CH(3)O)O(CH(3)OH)], features a vanadyl group, a tridentate Schiff base ligand, and coordinated methanol and methano-late ligands. The NO(5) donor set is based on a distorted octa-hedron. Helical supra-molecular chains along [010] are found in the crystal structure mediated by O-H⋯O hydrogen bonds formed between the coordinating methanol mol-...
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